Did they perhaps change the encryption or the password? The first time you connect to a password protected wireless connection Mac OS X will cache that password in the keychain (this explains why you didn't need to enter it the second time you visited). However, if the password has changed then Mac OS X will keep trying to use the cached one. Go into /Applications/Utilities and look for Keychain. Open it, find the Wireless network you connected to previously and delete its entry. The next time you go to the Library it will prompt you for the password again. Make sure its correct and try it.
Trev